Study reveals surprisingly simple method for determining exchange energy in 2D materials

Researchers from the University of Basel have looked at how the ferromagnetic properties of electrons in the two-dimensional semiconductor molybdenum disulfide can be better understood. They revealed a surprisingly simple way of measuring the energy needed to flip an electron spin.
Ferromagnetism is an important physical phenomenon that plays a key role in many technologies. It is well-known that metals such as iron, cobalt and nickel are magnetic at room temperature because their electron spins are aligned in parallel鈥攁nd it is only at very high temperatures that these materials lose their magnetic properties.
Researchers led by Professor Richard Warburton of the Department of 萌妹社区ics and the Swiss Nanoscience Institute of the University of Basel have shown that molybdenum disulfide also exhibits ferromagnetic properties under certain conditions. When subjected to low temperatures and an external magnetic field, the electron spins in this material all point in the same direction.
In their latest study, in the journal 萌妹社区ical Review Letters, the researchers determined how much energy it takes to flip an individual electron spin within this ferromagnetic state. This exchange energy is significant because it describes the stability of the ferromagnetism.
Detective work yields a simple solution
"We excited molybdenum disulfide using a laser and analyzed the spectral lines it emitted," explains Dr. Nadine Leisgang, main author of the study. Given that each spectral line corresponds to a specific wavelength and energy, the researchers were able to determine the exchange energy by measuring the separation between specific spectral lines.
They found that in molybdenum disulfide, this energy is only about 10 times smaller than in iron鈥攊ndicating that the material's ferromagnetism is highly stable.
"Although the solution seems simple, it took considerable detective work to allocate the spectral lines correctly," says Warburton.
Two-dimensional materials
2D materials play a key role in materials research thanks to their special physical properties, which are the result of quantum mechanical effects. They can also be stacked to form van der Waals heterostructures.
In the example seen in this study, the molybdenum disulfide layer is surrounded by hexagonal boron nitride and graphene. These layers are held together by weak van der Waals bonds and are of interest in the fields of electronics and optoelectronics thanks to their unique properties. Understanding their electrical and optical properties is vital in order to apply them to future technologies.
More information: Nadine Leisgang et al, Exchange Energy of the Ferromagnetic Electronic Ground State in a Monolayer Semiconductor, 萌妹社区ical Review Letters (2024).
Journal information: 萌妹社区ical Review Letters
Provided by University of Basel